As a measure of the material disposition for the absorption of the free component, an innovative term of plutability is proposed, which allows the introduction of various forecaster variables such as temperature, pressure, and activity. For the associated thermodynamic definition of the mobile component, the previously formulated hyperfree energy function, which was recently applied to several systems, was used. A gradual increase in thermodynamic concepts related to solid-state description is investigated in more detail. Holba in the initial phase definition and related characterization of partially open systems. Korzhinskiĭ and further developed by Czech P. Founding and construction of thermodynamic functions related to solid (geologic, metallurgic) materials is traced showing interactions between Czech Professor F. Nonstoichiometric oxides form a new chapter in tailored materials.
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